Antioxidant D
N-phenyl-2-naphthylamine
CAS: 135-88-6
Molecular Formula: C16H13N
Antioxidant D - Names and Identifiers
| Name | N-phenyl-2-naphthylamine |
| Synonyms | nonoxd Nonox D nonoxdn nocracd Nonox DN Antioxidant D N-2-NAPHTHYLANILINE N-2-Naphthylaniline Phenylnaphthylamine Nonox DNStabilizer AR N-Phenyl-2-naphttylamine N-phenyl-2-naphthylamine N-phenylnaphthalen-1-amine N-phenylnaphthalen-2-amine N-PHENYL-BETA-NAPHTHYLAMINE N-tert-butyl-N-[(Z)-phenylmethylidene]amine oxide |
| CAS | 135-88-6 |
| EINECS | 205-223-9 |
| InChI | InChI=1/C11H15NO/c1-11(2,3)12(13)9-10-7-5-4-6-8-10/h4-9H,1-3H3/b12-9- |
Antioxidant D - Physico-chemical Properties
| Molecular Formula | C16H13N |
| Molar Mass | 219.28 |
| Density | 1.24 |
| Melting Point | 105-108 °C (lit.) |
| Boling Point | 395-395.5 °C (lit.) |
| Flash Point | 118.47°C |
| Water Solubility | Insoluble. |
| Solubility | Chloroform (Slightly), Methanol (Very Slightly) |
| Vapor Presure | 0.001Pa at 20℃ |
| Appearance | Gray to tan flakes or powder |
| Color | Pale Beige to Pale Gray |
| BRN | 2211188 |
| pKa | 0.78±0.30(Predicted) |
| Storage Condition | -20°C |
| Stability | Stable. Incompatible with oxidizing agents. |
| Refractive Index | 1.7020 (estimate) |
| Physical and Chemical Properties | Light gray powder that gradually turns gray-red when exposed to air or sunlight. |
| Use | Suitable for natural rubber, synthetic rubber and latex |
Antioxidant D - Risk and Safety
| Risk Codes | R36/38 - Irritating to eyes and skin. R40 - Limited evidence of a carcinogenic effect R43 - May cause sensitization by skin contact R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53 - May cause long-term adverse effects in the aquatic environment R51 - Toxic to aquatic organisms |
| Safety Description | S22 - Do not breathe dust. S24/25 - Avoid contact with skin and eyes. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. S36/37 - Wear suitable protective clothing and gloves. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| UN IDs | 3077 |
| WGK Germany | 2 |
| RTECS | QM4550000 |
| HS Code | 29214500 |
| Hazard Class | 6.1(b) |
| Packing Group | III |
Antioxidant D - Upstream Downstream Industry
| Raw Materials | 2-Naphthol Aniline Hydrochloric acid |
Antioxidant D - Reference Information
| LogP | 3.2 at 23℃ and pH7.9-8.3 |
| NIST chemical information | Information provided by: webbook.nist.gov (external link) |
| (IARC) carcinogen classification | 3 (Vol. 16, Sup 7) 1987 |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| use | suitable for natural rubber, synthetic rubber and latex this product is a universal antioxidant for natural rubber, diene synthetic rubber, neoprene rubber and base latex. It has a good protective effect on heat, oxygen, flexing and general aging, and is slightly better than the anti-aging agent A. It has an inhibitory effect on harmful metals, but it is weaker than the anti-aging agent. If combined with antioxidant 4010 or 4010NA, the resistance to heat, oxygen, flex and crack, and the resistance to ozone are significantly improved. This product has no effect on the vulcanization speed of natural rubber, nitrile rubber and styrene butadiene rubber, but has a slight delay effect on chloroprene rubber. This product is easy to decompose in dry glue and disperse in water. The solubility of this product in rubber is about 1.5%, and no frost spraying will occur if the dosage does not exceed 1 part. The product is polluting and gradually turns gray-black in sunlight, so it is not suitable for white or light-colored products. It is mainly used to manufacture industrial products such as tires, rubber hoses, adhesive tapes, rubber rollers, rubber shoes, wire and cable insulation layers. Anti-aging agent butyl can also be used as a stabilizer for various synthetic rubber post-treatment and storage, and can be used as a heat-resistant anti-aging agent for polyoxymethylene. The product has a certain irritation to the skin. test chlorate. Organic synthesis. Dye intermediates. Used as rubber antioxidant, lubricant, polymerization inhibitor. |
| Production method | 2-naphthol and aniline are condensed at 250 ℃ under the catalysis of aniline hydrochloride. Add 2-naphthol and benzene to the condensation pot to melt, and add aniline hydrochloride for condensation. After the reaction is over, neutralize with sodium carbonate. Excessive aniline is steamed out, then dehydrated and dried under vacuum, and the antioxidant is obtained by slicing, powdering and packaging. Raw material consumption (kg/t)2-naphthol (98.5%) 660 aniline (99.2%) 425 |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 21:22:08
Supplier List
Spot supply
Product Name: N-phenyl-2-naphthylamine Request for quotationCAS: 135-88-6
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Spot supply
Product Name: N-phenyl-2-naphthylamine Request for quotationCAS: 135-88-6
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
View History
Raw Materials for Antioxidant D